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Hydrogen Mirror 5/97

News from Hydrogen and Fuel Cell

compiled by the German Hydrogen Association

 

The topics of issue 5/97:
Hydrogen

 

Fuel Cells

 

Politics

 

Seen Elsewhere

 

 

 


Hydrogen

 

Graphite fiber storage
At the end of 1996 the two Boston chemists Rodriguez and Baker had reported that certain graphite fibers with dimensions in the nm range could store astonishing amounts of hydrogen (see nos. 2/97 and 3/97). They meanwhile hold a patent on various graphite nanostructures, a device using them for the storage of hydrogen, and the process for them. The US department of energy (DoE) supports the work with 175 k$ and maybe 45 k$ more later.

Daimler-Benz cooperates "closely" with Rodriguez and Baker, but is silent about the results.We hear that Daimler will soon verify the basic results of the investigations from Boston with amounts between 200 mg and 1 kg.

In Germany the Center for Solar Energy and Hydrogen Research (ZSW) in Ulm and other partners have made measurements of their own with carbon fibers. Juergen Garche of ZSW is optimistic about the probable results.

Common typical feature of all graphite nanostructures suitable for hydrogen storage is a high percentage of crystalline graphite and distances or gaps with a size as close as possible to 0.335 nm. The pi electrons of the C atom are delocalized in the graphite crystal. So the lattice has a common cloud of electrons, similar to metals and unlike amorphous activated charcoal. This permits chemisorption of gas or vapor molecules, which results in a much stronger bonding than in the case of physisorption on activated charcoal or comparable substances.

Quite independent of hydrogen storage there are already numerous other applications for graphite fibers. The price for the fibers under the conditions of mass production is not seen as critical.

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Liquid hydrogen by sea
Germanischer Lloyd in Hamburg is doing the numerical evaluation of the experiments made on a model tank for liquid hydrogen (LH2) which were made in 1996 on the test ground Horstwalde of the Federal Institute for Materials Research and Testing (BAM, see no. 2/97). The experiments gave indications about how do design very large containers (3600 m3) for the sea transport of LH2. The comparison with the measurements permitted also the validation of numerical models so that a much better prediction of the pressure rise is now possible. The results can be transferred to other cryogenic liquid gases like nitrogen, oxygen, or natural gas.

After the end of the experiments the model tank stands "unemployed" on the test BAM ground 50 km S of Berlin; its use by other interested parties for research purposes will principally be permitted.

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Standardization
The Technical Committee 197 "Hydrogen Technologies" of the International Organization for Standardization (ISO) held its regular meeting in May in Toronto. The US delegation proposed two new topics dealing with vehicles running on hydrogen. The industrial association (NHA), which dominates the US delegation, has a great interest in the introduction of hydrogen fuel in traffic. A proposal of the German delegation for a safety standard was submitted and approved.

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Conference
The conference "Hypothesis II" was held in Grimstad, Norway, with international participation from 18. to 22. August.

H. Buchner (Daimler-Benz) reported about the state of the project by Daimler-Benz and several partners, mainly medium enterprises from Thuringia, for the use of hydrogen as fuel for utility vehicles and for the reduction of the NOx emissions of Diesel motors.

The former Los Alamos member W. Edeskuty gave a presentation about the connection between safety and public acceptance of hydrogen technology. He demanded general and international standards and rules (see the note about the ISO groups).

The national hydrogen associations, in particular those from Europe, will improve and also formalize their cooperation.

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Running on water
There are a few cars running on hydrogen, but cars with water tanks??? Of course, when the water could e split somehow on board of the vehicle ...

Under the title "Renaissance Project" a committee of the US National Hydrogen Association (NHA) thinks seriously about mobility and vehicles of the next century and also considers filling up your car from the water hose. A planning group will have its first meeting in autumn.

By the way: the July issue of the "International Journal of Hydrogen Energy" (page 675) reports about "Photoelectrocatalytical production of hydrogen from natural sea water with sunlight". A yield of up to 400 cm3/h gas is possible per m2 radiated area.

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Aviation
A Boeing 747 of TWA with 230 passengers on board crashed on 17. July 1996 off the coast of Long Island. A final result of the investigation is not yet available. It appears to be clear that the kerosene vapor / air mixture in the almost empty main tank exploded and caused the accident. Where the ignition energy came from is not settled.
Remark: Air in the tank is the normal state for kerosene aircraft as well as gasoline card. Under normal conditions the concentration of the mixture is too high, but when the tank is almost empty the explosive range can be reached. Hydrogen tanks contain no air at all under normal conditions, so that an ignition is impossible even if energy is supplied. In spite of a common prejudice transportation running on hydrogen is not only not more dangerous, but may even be safer than with conventional fuels.
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Fuel Cells

 

Hamburg
The new hydrogen fuel cell of the joint team of Hamburgische Electricitaets-Werke / Hamburger Gaswerke at Lyserstr. in Hamburg-Bahrenfeld was officially inaugurated on 14. August. It is a phosphoric acid cell with 200 kWel and 200 kWth nominal out which is fed with liquid hydrogen from an upright tank. The total efficiency is 85 %. It supplements a similar plant which runs since autumn 1985 on natural gas from the city grid without problems. Both are part of a heating station which supplies 600 flats. Heat demand which exceeds the fuel cell power is covered conventionally, and the electrical energy of the aggregates is fed in the Hamburg grid. There are no problems with the public; tenants in the houses connected to the cells rather appear to be proud of "their" plant and the many groups of visitors.

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ONSI - Correction
The US fuel cell manufacturer ONSI had in July a total of 185 orders for cells of the type PC 25. It was not the number of new orders, as erroneously reported in the last issue. We are sorry for our mistake.

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Subsidiaries USA
The US department of energy (DoE) supports the purchase of fuel cells in order to enhance the market chances of this technology. A phosphorous fuel cell with 200 kWel nominal power costs today about 600 k$. A price of 400 k$ is considered as competitive. The DoE has reserved 15 M$ to support (US) customers with 1000 $/kW up to 1/3 of the price of the plant. The rise of the number of orders (see above) shows that it works rather well. The manufacturers think that with a demand like this they can by means of greater volume of production reduce the costs such that in 2000 they will be able to sell them for 400 k$ without subsidiaries. Their problem in the moment is rather a lack of capacity. (Source: Hydrogen & Fuel Cell Letter)

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Cars - Renault
In connection with the Hypothesis II in Grimstad Renault and partners showed the state of the project "FEVER" (car with LH2 tank and PEM cell). Test drives are scheduled for this year. In a parallel development Peugeot develops a similar vehicle with a pressure tank and an even smaller PEM cell. Both activities are supported by the EU.

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Cars - Toyota
On the IAA in Frankfurt/Main Toyota presented the present state of development of the fuel cell which was first shown in 1996 (see no. 1/97). Instead of the former metal hydride storage is now has a methanol tank, a reformer, an improved PEM cell (25 kW) and a buffer battery.

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Cars - Daimler-Benz
Reacting to the Toyota presentation Daimler-Benz presented its NECAR 3 to the public for the first time on 10. September on the IAA at Frankfurt. A more formal presentation will be held in October in Tokyo, as we had already written in no. 4/97. Chairman Schrempp stressed that Daimler's intention is to be the first manufacturer on the market with a serial fuel cell car. Other statements were that serial production could start 2004 or 2005.

The partnership Daimler/Ballard which was agreed in April (see no. 3/97) is now formal since 26. August. The contracts about a capital investment and the foundation of joint daughter companies for development and marketing of fuel cell drives were signed. During the next months both sides together will invest more than 450 MCan$ (about 290 MEuro). Board member Hubbert, responsible for cars, said for Daimler during the signing ceremony that the fuel cell "has the greatest chances to make serious competition to the combustion engine". Car development head Petri said: "The fuel cell will prevail, when we are able to offer them to our customers to an attractive relation of price and performance."

The "Project House Fuel Cell" of Daimler-Benz AG now has a spacious new quarter at Nabern near Kirchheim unter Teck. All activities on the fuel cell car system in Esslingen, Ulm, Friedrichshafen, and elsewhere have been concentrated there.

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Politics

 

Federal Environment Agency
On 18. September 1997 a discussion was held between energy and transportation experts of the Federal Environment Agency (UBA) in Berlin and members of the board of DWV in the house of the former. There was agreement that UBA and DWV will cooperate in matters of common interest, in particular that they will exchange information.

UBA principally investigates all environmental relevant technologies, but makes a difference between those which promise a progress now or in the foreseeable future and those which might find a broad application at a later time. It is reluctant for the time being as far as the possibilities of hydrogen technology are concerned, especially when the necessary energy and the emissions are considered for the whole process chain including the hydrogen production. UBA has an interest, however, in keeping open the option of hydrogen technology and in investigating it in well-defined application projects.

The transportation department of the agency advocated that the use of hydrogen fuel is not necessary for the reduction of the limited emissions (hydrocarbons, CO, NOx, particulate matter). The way to the decrease of CO2 emissions is rather seen in the reduction of consumption. Fuel cell application is rather seen in the stationary domain, where for the time being fossil fuels should be used preferably as primary fuels.

The news about UBA's reaction on the presentation of Daimler-Benz's Nebus had caused a certain irritation. UBA said that this was due to a wrong impression of UBA's evaluation of fuel cell technology which was caused by shortened media reports giving a wrong picture. UBA's expectations, however, are in fact not quite as high as those in the Daimler press releases. By no means, however, is the house against hydrogen and fuel cells.

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Berlin
Environment senator Strieder does not consider the Bavarian support for hydrogen technology (see no. 4/97) as a model for Berlin, does not make any promises about the use of the money from the sale of state owned shares in certain companies, and does not think that specific support is necessary. Any available money would be used with preference for the promotion of solar energy. This is the essence from his answer to a parliamentary inquiry. The senator said that the activities in Japan and the USA are not known to him.

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Lobby
DWV is now on the list kept by the president of the federal parliament of associations who represent interests toward the parliament or the federal government.

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Seen Elsewhere

 

Old stuff
DER SPIEGEL reports in issue 35/97 that Daimler-Benz will take over 25 % from Ballard, together with Ballard invests 200 MEuro in fuel cell driving systems, and will present the NECAR 3 in October in Tokyo.
Remark: Oh, how exciting news this would be, if we would not have read it months ago in the Hydrogen Mirror or in the HyWeb. Note: Our readers are even better informed!
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Hydrogen Mirror 5/97
Published by German Hydrogen Association, Berlin
Editor: Ulrich Schmidtchen, Berlin